Source:http://linkedlifedata.com/resource/pubmed/id/12562201
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
3
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| pubmed:dateCreated |
2003-2-3
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| pubmed:abstractText |
The structure, spectroscopy, and magnetism of a century-old copper salt, Cu(OAc)(OMe), is reported. The crystal structure contains two independent Cu(II) ions, which are both five-coordinated and which are bridged by methoxo and acetate anions to form an infinite 2D network. Thereby the methoxo groups connect Cu1 and Cu2 with their symmetry-generated counterparts Cu1(i) and Cu2(i), respectively, resulting in Cu.Cu distances of 2.9803(10) and 2.9874(10) A. Cu1 and Cu2 themselves are bridged via the carboxylate groups of two acetates leading to a Cu1.Cu2 distance of 2.9473(7) A. The tetranuclear units thus generated are cross-linked via acetate oxygens to form a 2D sheet structure. One of the two independent acetate ligands has a rare binding mode, whereby it acts as a tetradentate syn-anti, syn-anti bridging ligand. The temperature dependence of the magnetic susceptibility was assigned to be dominated by the very strong antiferromagnetic exchange coupling via bis(mu-methoxo) bridges (J(1) = -409(1) cm(-)(1)).
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
10
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| pubmed:volume |
42
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
868-72
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| pubmed:dateRevised |
2004-4-8
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| pubmed:year |
2003
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| pubmed:articleTitle |
Century-known copper salt Cu(OAc)(OMe) proven to be a unique magnetic lattice composed of tetranuclear copper(II) species with a rare binding mode of the acetate anion.
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| pubmed:affiliation |
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, 2300 RA Leiden, The Netherlands.
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| pubmed:publicationType |
Journal Article
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