12558415

Source:http://linkedlifedata.com/resource/pubmed/id/12558415

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0037494, umls-concept:C0205360, umls-concept:C0205374
pubmed:issue	3
pubmed:dateCreated	2003-1-31
pubmed:abstractText	Catalytic amounts of a protic reagent such as tert-butyl alcohol promote the isomerization of a stable amino-aryl-carbene into a transient azomethine ylide. Deprotonation of an alkyl-aldiminium salt also leads to a transient azomethine ylide, but labeling experiments rule out the transient formation of the corresponding amino-alkyl-carbene. The potential hypersurface between model amino-carbene, aziridine, and azomethine ylide is investigated.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Feb
pubmed:issn	0022-3263
pubmed:author	pubmed-author:BertrandGuyG, pubmed-author:BourissouDidierD, pubmed-author:CattoënXavierX, pubmed-author:GornitzkaHeinzH, pubmed-author:MiqueuKarinneK, pubmed-author:PradelChristianC, pubmed-author:SoléStéphaneS
pubmed:issnType	Print
pubmed:day	7
pubmed:volume	68
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	911-4
pubmed:year	2003
pubmed:articleTitle	Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt.
pubmed:affiliation	Laboratoire d'Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 04, France.
pubmed:publicationType	Journal Article