Source:http://linkedlifedata.com/resource/pubmed/id/12466607
| Subject | Predicate | Object | Context |
|---|---|---|---|
| pubmed-article:12466607 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:12466607 | lifeskim:mentions | umls-concept:C0028013 | lld:lifeskim |
| pubmed-article:12466607 | lifeskim:mentions | umls-concept:C0077281 | lld:lifeskim |
| pubmed-article:12466607 | pubmed:issue | Pt 12 | lld:pubmed |
| pubmed-article:12466607 | pubmed:dateCreated | 2002-12-5 | lld:pubmed |
| pubmed-article:12466607 | pubmed:abstractText | The title complex, ([Ni(C(2)H(8)N(2))(3)][Na(NCS)(3)(H(2)O)])(n), consists of discrete [Ni(en)(3)](2+) dications (en is ethylenediamine) and polymeric [(H(2)O)(0.5)Na(NCS)(3)(H(2)O)(0.5)](n)(2n-) anions. The compound crystallizes in space group P-3c1. The Ni(II) atom lies on a threefold axis and has a distorted octahedral coordination geometry. The Na(+) cation also lies on a site with imposed crystallographic threefold symmetry and is coordinated by the thiocyanate N atoms (the thiocyanates are in general positions), by one water molecule with crystallographically imposed 32 symmetry and by a second water molecule with crystallographically imposed -3 symmetry. The unique Na atom thus has trigonal-bipyramidal coordination. The O atoms of the water molecules bridge the Na(+) cations to form one-dimensional polymeric chains in the crystal structure. The [Ni(en)(3)](2+) dications are distributed around and between the chains and are linked to them via N-H.S hydrogen bonds. | lld:pubmed |
| pubmed-article:12466607 | pubmed:language | eng | lld:pubmed |
| pubmed-article:12466607 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12466607 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:12466607 | pubmed:month | Dec | lld:pubmed |
| pubmed-article:12466607 | pubmed:issn | 0108-2701 | lld:pubmed |
| pubmed-article:12466607 | pubmed:author | pubmed-author:ShenLiangL | lld:pubmed |
| pubmed-article:12466607 | pubmed:author | pubmed-author:JingZhi MinZM | lld:pubmed |
| pubmed-article:12466607 | pubmed:issnType | lld:pubmed | |
| pubmed-article:12466607 | pubmed:volume | 58 | lld:pubmed |
| pubmed-article:12466607 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:12466607 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:12466607 | pubmed:pagination | m591-2 | lld:pubmed |
| pubmed-article:12466607 | pubmed:dateRevised | 2003-11-4 | lld:pubmed |
| pubmed-article:12466607 | pubmed:year | 2002 | lld:pubmed |
| pubmed-article:12466607 | pubmed:articleTitle | catena-Poly[tris(ethylenediamine-kappa2N,N')nickel(II) [[trithiocyanato-kappa3N-sodium(I)]-mu-aqua-kappa2O:O]]. | lld:pubmed |
| pubmed-article:12466607 | pubmed:affiliation | Department of Chemistry, Hangzhou Teachers' College, Hangzhou 310012, People's Republic of China. shenchem@sina.com | lld:pubmed |
| pubmed-article:12466607 | pubmed:publicationType | Journal Article | lld:pubmed |