Source:http://linkedlifedata.com/resource/pubmed/id/12466607
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 12
|
| pubmed:dateCreated |
2002-12-5
|
| pubmed:abstractText |
The title complex, ([Ni(C(2)H(8)N(2))(3)][Na(NCS)(3)(H(2)O)])(n), consists of discrete [Ni(en)(3)](2+) dications (en is ethylenediamine) and polymeric [(H(2)O)(0.5)Na(NCS)(3)(H(2)O)(0.5)](n)(2n-) anions. The compound crystallizes in space group P-3c1. The Ni(II) atom lies on a threefold axis and has a distorted octahedral coordination geometry. The Na(+) cation also lies on a site with imposed crystallographic threefold symmetry and is coordinated by the thiocyanate N atoms (the thiocyanates are in general positions), by one water molecule with crystallographically imposed 32 symmetry and by a second water molecule with crystallographically imposed -3 symmetry. The unique Na atom thus has trigonal-bipyramidal coordination. The O atoms of the water molecules bridge the Na(+) cations to form one-dimensional polymeric chains in the crystal structure. The [Ni(en)(3)](2+) dications are distributed around and between the chains and are linked to them via N-H.S hydrogen bonds.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Dec
|
| pubmed:issn |
0108-2701
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
58
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
m591-2
|
| pubmed:dateRevised |
2003-11-4
|
| pubmed:year |
2002
|
| pubmed:articleTitle |
catena-Poly[tris(ethylenediamine-kappa2N,N')nickel(II) [[trithiocyanato-kappa3N-sodium(I)]-mu-aqua-kappa2O:O]].
|
| pubmed:affiliation |
Department of Chemistry, Hangzhou Teachers' College, Hangzhou 310012, People's Republic of China. shenchem@sina.com
|
| pubmed:publicationType |
Journal Article
|