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rdf:type
lifeskim:mentions
pubmed:dateCreated
2002-11-19
pubmed:abstractText
We provide a summary of our results in three-dimensional, coordination-driven self-assembly based on the directional-bonding methodology, in which the stoichiometric mixing of complementary building blocks, with appropriate, predefined geometries, leads to targeted, nanoscopic cages. Using this motif, we have synthesized high-symmetry ensembles resembling the Platonic solids, such as dodecahedra, and the Archimedean solids, such as truncated tetrahedra and cuboctahedra, as well as other cages, like trigonal bipyramids, adamantanoids, and trigonal prisms. The synthesis and characterization of these compounds is discussed, as is some host-guest chemistry.
pubmed:grant
pubmed:language
eng
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:author
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
972-83
pubmed:dateRevised
2007-11-14
pubmed:articleTitle
High-symmetry coordination cages via self-assembly.
pubmed:affiliation
Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, USA.