Source:http://linkedlifedata.com/resource/pubmed/id/12430489
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:dateCreated |
2002-11-14
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| pubmed:abstractText |
Density functional theory calculations on [LnCp2APh] (Ln = La, Lu; Cp = eta 5-C5H5; A = O, S; Ph = C6H5) suggest that the linearity of the Ln-O-C vectors arises largely as a result of electrostatic repulsion between the alpha carbon and the trivalent metal centre.
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| pubmed:language |
eng
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| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:author | |
| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
2458-9
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| pubmed:articleTitle |
Are metal alkoxides linear owing to electrostatic repulsion?
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| pubmed:affiliation |
Department of Chemistry, University College London, 20 Gordon Street, London, UK.
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