Source:http://linkedlifedata.com/resource/pubmed/id/12398526
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
22
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pubmed:dateCreated |
2002-10-25
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pubmed:abstractText |
Reduction of (+/-)-5-chloro-5-methyl-2-cyclopentenone with BH(3).THF and catalytic (R)-2-methyl-CBS-oxazaborolidine gave readily separable diastereomers with high ee values. Oxidation of the diastereomers furnished the enantiomers of the chloromethylcyclopentenone.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Nov
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pubmed:issn |
0022-3263
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
1
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
7902-3
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pubmed:year |
2002
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pubmed:articleTitle |
Resolution of both enantiomers of 5-chloro-5-methyl-2-cyclopentenone.
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pubmed:affiliation |
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla 92093-0506, USA. tmcmorris@ucsd.edu
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pubmed:publicationType |
Journal Article
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