Linked Life Data

12212745

Source:http://linkedlifedata.com/resource/pubmed/id/12212745

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
10
pubmed:dateCreated
2002-9-5
pubmed:abstractText
New bidentate N-(2,5-di-tert-butylphenyl)salicylaldimines bearing X = H, HO, CH3O, Br, NO2, 3,5-di-Br, 3-NO2-5-Br and 5,6-benzo substituents on the salicylaldehyde moiety, LxH, and their mononuclear bis[N-(2,5-di-tert-butylphenyl)salicylaldiminato]copper(II) complexes, Cu(Lx)2, have been prepared and investigated by IR, UV-Visible, 1H NMR, ESR spectroscopy, magnetic measurements, as well as reactions of Cu(LX)2 with PPh3 were studied. It has been found that some complexes with X = HO and CH3O unlike their electron-withdrawing and unsubstituted analogues are readily reduced by PPh3 via intramolecular electron transfer from ligand to copper(II) to give Cu-stabilized radical intermediates. The spectra of the primary radicals interpreted in terms of couplings of unpaired electron with (63,65)Cu, 31P, 14N nuclei and aromatic protons.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1386-1425
pubmed:author
pubmed:issnType
Print
pubmed:volume
58
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2199-211
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Synthesis, spectroscopic characterization and EPR studies on electron transfer reactions of bis[N-(2,5-di-tert-butylphenyl)salicylaldiminato]copper complexes with PPh3.
pubmed:affiliation
Department of Chemistry, Faculty of Arts and Sciences, Harran University, Sanliurfa, Turkey. vkasumov@harran.edu.tr
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't