Linked Life Data

12200842

Source:http://linkedlifedata.com/resource/pubmed/id/12200842

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2002-8-30
pubmed:abstractText
The anion-selectivity of the surface of a polymer ultrathin film incorporating an amphiphilic ruthenium(II) polypyridine complex with diperchlorate was examined using X-ray absorption spectroscopy with the total electron-yield method. The adsorbed species on the film surface were found to depend on the chemical composition in water where the film was prepared. By combining the X-ray absorption spectra with a molecular-orbital calculation, the molar ratio (MClO4/MRu) between the ClO4- ions and the Ru head group on the film surface could be semi-quantitatively analyzed; it was 0.88 for a film prepared on fresh water, and 1.4 for one prepared on old water.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
0910-6340
pubmed:author
pubmed:issnType
Print
pubmed:volume
18
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
927-30
pubmed:year
2002
pubmed:articleTitle
X-ray absorption spectral studies on the anion-selectivity of a ruthenium(II) polypyridine complex-impregnated polymer ultrathin film.
pubmed:affiliation
Advanced Materials Institute, Fukuoka University, Nanakuma, Jonan, Fukuoka 814-0180, Japan. mashu23@hotmail.com
pubmed:publicationType
Journal Article