Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6 Pt 1
pubmed:dateCreated
2002-8-21
pubmed:abstractText
Motivated by results from an earlier Brownian dynamics simulation for the collapse of a single, stiff polymer in a poor solvent [B. Schnurr, F. C. MacKintosh, and D. R. M. Williams, Europhys. Lett. 51, 279 (2000)] we calculate the conformational energies of the intermediate (racquet) states suggested by the simulations. In the absence of thermal fluctuations (at zero temperature) the annealed shapes of these intermediates are well-defined in certain limits, with their major structural elements given by a particular case of Euler's elastica. In appropriate units, a diagram emerges that displays the relative stability of all states, tori, and racquets. We conclude that, in marked contrast to the collapse of flexible polymers, the condensation of semiflexible or stiff polymers generically proceeds via a cascade through metastable intermediates, the racquets, towards a ground state, the torus or ring, as seen in the dynamical simulations.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1539-3755
pubmed:author
pubmed:issnType
Print
pubmed:volume
65
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
061904
pubmed:dateRevised
2003-11-3
pubmed:year
2002
pubmed:articleTitle
Metastable intermediates in the condensation of semiflexible polymers.
pubmed:affiliation
Department of Physics and Biophysics Research Division, University of Michigan, Ann Arbor, Michigan 48109-1120, USA. bernhard.schnurr@wiezmann.ac.il
pubmed:publicationType
Journal Article