Source:http://linkedlifedata.com/resource/pubmed/id/12153279
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
16
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pubmed:dateCreated |
2002-8-2
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pubmed:abstractText |
An efficient and general oxidative demetalation of (eta(3)-allyl)molybdenum complexes using pyridinium dichromate allows the introduction of a carbonyl group at an allylic terminus of the pi-system. The process takes place with high regiocontrol and can lead to the preparation of unsaturated ketones and lactones of high enantiopurity.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
0022-3263
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
9
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5773-8
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pubmed:dateRevised |
2007-11-14
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pubmed:meshHeading |
pubmed-meshheading:12153279-Ketones,
pubmed-meshheading:12153279-Lactones,
pubmed-meshheading:12153279-Models, Molecular,
pubmed-meshheading:12153279-Molecular Conformation,
pubmed-meshheading:12153279-Molybdenum,
pubmed-meshheading:12153279-Stereoisomerism,
pubmed-meshheading:12153279-Structure-Activity Relationship
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pubmed:year |
2002
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pubmed:articleTitle |
New oxidative demetalation protocol for molybdenum pi-complexes: enantiocontrolled synthesis of unsaturated ketones and lactones.
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pubmed:affiliation |
Department of Chemistry, Emory University, 1515 Pierce Drive, Atlanta, Georgia 30322, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, P.H.S.,
Research Support, Non-U.S. Gov't
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