12153214

Source:http://linkedlifedata.com/resource/pubmed/id/12153214

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0002068, umls-concept:C0009968, umls-concept:C0969469
pubmed:issue	16
pubmed:dateCreated	2002-8-2
pubmed:abstractText	[reaction: see text] An unprecedented copper phosphoramidite catalyzed enantioselective alkylative ring-opening reaction of oxabenzonorbornadiene derivatives with dialkylzinc reagents is reported. The reaction shows high levels of anti-stereoselectivity (up to anti/syn >99:1), complementary to the Pd(0)-catalyzed syn-selective ring-opening protocol, allowing a new entry to anti-dihydronaphthols with high enantioselectivity (up to 99% ee).
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Aug
pubmed:issn	1523-7060
pubmed:author	pubmed-author:ArnoldLeggy ALA, pubmed-author:BertozziFabioF, pubmed-author:FeringaBen LBL, pubmed-author:MacchiaFrancoF, pubmed-author:MinnaardAdriaan JAJ, pubmed-author:PineschiMauroM
pubmed:issnType	Print
pubmed:day	8
pubmed:volume	4
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2703-5
pubmed:dateRevised	2003-11-3
pubmed:year	2002
pubmed:articleTitle	Copper phosphoramidite catalyzed enantioselective ring-opening of oxabicyclic alkenes: remarkable reversal of stereocontrol.
pubmed:affiliation	Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, The Netherlands.
pubmed:publicationType	Journal Article