Linked Life Data

12105907

Source:http://linkedlifedata.com/resource/pubmed/id/12105907

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
28
pubmed:dateCreated
2002-7-10
pubmed:abstractText
Photophysical measurements, recorded in aerated cyclohexane at 283 K, indicate that 1,4-bis(phenylethynyl)benzene behaves in a conventional manner, undergoing emission from the lowest vibrational level of the first excited singlet state; there is no evidence for aggregation of this material in cyclohexane solution in the concentration range (1-250) x 10(-6) mol dm(-3). However, in highly viscous, low-temperature glasses, the material does exhibit inhomogeneous fluorescence behavior, and wavelength-dependent excitation and emission spectra, indicative of a slow rate of relaxation of conformers of the excited states compared to the rate of fluorescence.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
124
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8280-4
pubmed:dateRevised
2003-11-3
pubmed:year
2002
pubmed:articleTitle
A re-evaluation of the photophysical properties of 1,4-bis(phenylethynyl)benzene: a model for poly(phenyleneethynylene).
pubmed:affiliation
Department of Chemistry, University of Durham, Durham DH1 3LE, United Kingdom. Andrew.Beeby@durham.ac.uk
pubmed:publicationType
Journal Article