Linked Life Data

11992701

Source:http://linkedlifedata.com/resource/pubmed/id/11992701

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2002-5-6
pubmed:abstractText
The adsorption of mercury from aqueous solutions and chlor-alkali industry effluent on steam activated and sulphurised steam activated carbons prepared from bagasse pith have been studied comparatively. The uptake of mercury(II) (Hg(II)) was maximum by steam activated carbon in presence of SO(2) and H(2)S (SA-SO(2)-H(2)S-C) followed by steam activated carbon in presence of SO(2) (SA-SO(2)-C), steam activated carbon in presence of H(2)S (SA-H(2)S-C) and steam activated carbon (SA-C) at the same concentration, pH and temperature of the solution. Adsorption experiments demonstrate that the adsorption process corresponds to the pseudo-second-order kinetic model and equilibrium results correspond to the Langmuir adsorption isotherm. Kinetic parameters as a function of initial concentration, for all adsorbents were calculated. Batch studies indicated that the optimum pH range for the adsorption of Hg(II) on sulphurised carbons was between 4 and 9 and for sulphur free carbon was between 6 and 9 at 30 degrees C. The adsorptive behaviour of the activated carbons is explained on the basis of their chemical nature and porous texture. Decrease in ionic strength and increase in temperature of the solution has been found to improve the uptake of Hg(II). Synthetic and chlor-alkali industrial wastewaters were also treated by sulphurised activated carbons to demonstrate their efficiencies in removing Hg(II) from wastewaters. Some feasibility experiments have been carried out with a view to recover the adsorbed Hg(II) and regenerate the spent activated carbons using 0.2M HCl solution. The data obtained point towards viable adsorbents, which are both effective as well as economically attractive for Hg(II) removal from wastewaters.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
0304-3894
pubmed:author
pubmed:issnType
Print
pubmed:day
27
pubmed:volume
92
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
161-83
pubmed:dateRevised
2006-6-14
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Removal of mercury(II) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith: kinetics and equilibrium studies.
pubmed:affiliation
Department of Chemistry, University of Kerala, Kariavattom, 695581, Trivandrum, India.
pubmed:publicationType
Journal Article