rdf:type |
|
lifeskim:mentions |
|
pubmed:issue |
2
|
pubmed:dateCreated |
2002-5-6
|
pubmed:abstractText |
A kinetic flow-injection (FI) method is described for the determination of hydrogen peroxide. This method is based on an iron(III)-catalyzed oxidative coupling of 4-aminoantipyrine with N,N-dimethylaniline by hydrogen peroxide. By measuring the change in the absorbance of the dye formed at 560 nm, 1 x 10(-6) - 6 x 10(-4) M hydrogen peroxide could be determined with a sampling rate of 15 h(-1). The relative standard deviation (n = 30) was 0.8% for 5 x 10(-5) M hydrogen peroxide. There was little interference of the co-existing ions and compounds. After introducing some immobilized enzyme reactors to the FI system, the proposed method allowed the determination of glucose and uric acid ranging from 1 x 10(-6) to 6 x 10(-4) M with relative standard deviations of below 2%. The applicability of the method was demonstrated by determining these substances in serum samples.
|
pubmed:language |
eng
|
pubmed:journal |
|
pubmed:citationSubset |
IM
|
pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Ampyrone,
http://linkedlifedata.com/resource/pubmed/chemical/Aniline Compounds,
http://linkedlifedata.com/resource/pubmed/chemical/Blood Glucose,
http://linkedlifedata.com/resource/pubmed/chemical/Glucose Oxidase,
http://linkedlifedata.com/resource/pubmed/chemical/Hydrogen Peroxide,
http://linkedlifedata.com/resource/pubmed/chemical/Indicators and Reagents,
http://linkedlifedata.com/resource/pubmed/chemical/Iron,
http://linkedlifedata.com/resource/pubmed/chemical/N,N-dimethylaniline,
http://linkedlifedata.com/resource/pubmed/chemical/Urate Oxidase,
http://linkedlifedata.com/resource/pubmed/chemical/Uric Acid
|
pubmed:status |
MEDLINE
|
pubmed:month |
Feb
|
pubmed:issn |
0910-6340
|
pubmed:author |
|
pubmed:issnType |
Print
|
pubmed:volume |
17
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
255-8
|
pubmed:dateRevised |
2004-11-17
|
pubmed:meshHeading |
pubmed-meshheading:11990536-Ampyrone,
pubmed-meshheading:11990536-Aniline Compounds,
pubmed-meshheading:11990536-Blood Glucose,
pubmed-meshheading:11990536-Calibration,
pubmed-meshheading:11990536-Catalysis,
pubmed-meshheading:11990536-Flow Injection Analysis,
pubmed-meshheading:11990536-Glucose Oxidase,
pubmed-meshheading:11990536-Humans,
pubmed-meshheading:11990536-Hydrogen Peroxide,
pubmed-meshheading:11990536-Indicators and Reagents,
pubmed-meshheading:11990536-Iron,
pubmed-meshheading:11990536-Kinetics,
pubmed-meshheading:11990536-Photometry,
pubmed-meshheading:11990536-Urate Oxidase,
pubmed-meshheading:11990536-Uric Acid
|
pubmed:year |
2001
|
pubmed:articleTitle |
Kinetic flow-injection determination of hydrogen peroxide by use of iron(III)-catalyzed coloration and its application to the determination of biological substances.
|
pubmed:affiliation |
Department of Chemistry, University of Tsukuba, Japan.
|
pubmed:publicationType |
Journal Article
|