Linked Life Data

11971690

Source:http://linkedlifedata.com/resource/pubmed/id/11971690

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
17
pubmed:dateCreated
2002-4-24
pubmed:abstractText
A family of chiral molecular squares based on fac-Re(CO)3Cl metallocorners and enantiopure atropisomeric bipyridine bridging ligands (L1-4) have been synthesized in high yields by refluxing ClRe(CO)5 and L1-4 in 1:1 molar ratio. These novel chiral metallocycles have been characterized by 1H and 13C{1H} NMR, UV-vis, luminescence, and circular dichroism (CD) spectroscopies, FAB mass spectrometry, and microanalysis. Molecular square 4 which contains four 1,1'-bi-2-naphthol functionalities exhibits interesting enantioselective luminescence quenching by 2-amino-1-propanol. This research illustrates the potential of generating novel functional materials based on supramolecular chemistry.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
1
pubmed:volume
124
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4554-5
pubmed:dateRevised
2008-1-17
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
A chiral molecular square with metallo-corners for enantioselective sensing.
pubmed:affiliation
Department of Chemistry, CB # 3290, University of North Carolina, Chapel Hill, North Carolina 27599, USA.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't