Linked Life Data

11944688

Source:http://linkedlifedata.com/resource/pubmed/id/11944688

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2002-4-11
pubmed:abstractText
The degradation of 4-chlorophenol with near-UV light by silica-immobilized polyoxometalate (POM-in-SiO2) catalysts has been studied. The silica-immobilized Na6W7O24 (SW7), H4W1032 (SW10), H3PW12O40 (SPW12), and H6P2W18O62 (SP2W18) were prepared by means of the sol-gel hydrothermal technique through the hydrolysis of tetraethoxysilane in aqueous solution of the corresponding polyoxometalate, respectively. The degradation of 4-chlorophenol was monitored by measuring Cl- and CO2 concentrations and analyzing reaction intermediates by GC/MS analysis. During irradiation, 4-chlorophenol first dechlorinated to form hydroquinone and p-benzoquinone, and then these intermediates further mineralized to form CO2 and H2O. The degree to which 4-chlorophenol was mineralized by photocatalytic oxidation was investigated. Results indicate less than 15% for SW7 but nearly complete mineralization for SW10 after 60 min of photoirradiation. The present studies suggest that POM-in-SiO2 catalysts may be a novel type of photocatalyts for the purification of the environmentally chlorophenol-contaminated water.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0013-936X
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
36
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1325-9
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Photocatalytic degradation of aqueous 4-chlorophenol by silica-immobilized polyoxometalates.
pubmed:affiliation
Department of Chemistry, Fudan University, Shanghai, China. ymtianc@online.sh.cn
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't