Source:http://linkedlifedata.com/resource/pubmed/id/11932517
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 4
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| pubmed:dateCreated |
2002-4-4
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| pubmed:abstractText |
The title compound, [Cu(Cr(2)O(7))(C(10)H(8)N(2))(2)], a new mixed-metal molecular compound, contains isolated molecular units, each comprised of one Cu(II) atom coordinated to two 2,2'-bipyridine ligands and also to an oxygen vertex of a dichromate anion. The Cu(II) atom has an approximate trigonal-bipyramidal geometry, which is consistent with previous studies. Both enantiomers of the chiral complex molecule are present and are related by inversion centers. In a reported pyridine analogue, achiral [Cu(Cr(2)O(7))(pyridine)(4)] chains pack in the non-centrosymmetric space group Pna2(1). Differences in the organic ligands influence the chirality and dimensionality of the Cu-Cr(2)O(7) bonding.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
|
| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
58
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
M207-9
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| pubmed:dateRevised |
2003-11-3
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| pubmed:year |
2002
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| pubmed:articleTitle |
(2,2'-Bipyridine-kappa2N,N')(dichromato-kappaO)copper(II).
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| pubmed:affiliation |
Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
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| pubmed:publicationType |
Journal Article
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