Linked Life Data

11929075

Source:http://linkedlifedata.com/resource/pubmed/id/11929075

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2002-4-3
pubmed:abstractText
A number of chlorophenols, namely 2-chlorophenol, 2,4,-dichlorophenol and 2,4,6-trichlorophenol, were decomposed in aqueous solution by using TiO2 as photoactivated catalyst under UV radiation emitted by a 125W medium pressure Hg lamp in an immersion well-type quartz photoreactor. The organic-bound chlorine was converted into the environmentally harmless inorganic chloride. For catalyst doses between 0.1 and 0.5gl(-1) the reaction mechanisms are elucidated. The corresponding rate constants were obtained by periodically measuring the remaining chlorophenol, and converted chloride in solution. A theoretical model for the degradation pathway is proposed expressing the rate as a linear function of the concentrations of chlorophenol and catalyst. Aside from the model-calculated values, the pseudo-first order rate constants for a rough approximation of chlorophenols degradation as well as the kinetic parameters of Langmuir-Hinshelwood type decomposition are compared. The photodegradation rate of chlorophenols followed the order: C13 x Ph > Cl2 x Ph > Cl x Ph.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1093-4529
pubmed:author
pubmed:issnType
Print
pubmed:volume
37
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
365-83
pubmed:dateRevised
2009-8-14
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Kinetic studies on UV-photodegradation of some chlorophenols using TiO2 catalyst.
pubmed:affiliation
Department of Chemistry, Faculty of Engineering, Istanbul University, Avcilar, Turkey.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't