Source:http://linkedlifedata.com/resource/pubmed/id/11859187
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
5559
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pubmed:dateCreated |
2002-2-22
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pubmed:abstractText |
Isolable quantities of C60, the smallest stable fullerene, have been synthesized in 12 steps from commercially available starting materials by rational chemical methods. A molecular polycyclic aromatic precursor bearing chlorine substituents at key positions forms C60 when subjected to flash vacuum pyrolysis at 1100 degrees C. No other fullerenes are formed as by-products. The methods we have developed for the target-specific synthesis of fullerenes, applied here to a synthesis of C60, should make possible the directed laboratory preparation of other fullerenes as well, including those not accessible by graphite vaporization.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
1095-9203
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
22
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pubmed:volume |
295
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1500-3
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pubmed:dateRevised |
2007-3-19
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pubmed:year |
2002
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pubmed:articleTitle |
A rational chemical synthesis of C60.
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pubmed:affiliation |
Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467-3860, USA. lawrence.scott@bc.edu
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pubmed:publicationType |
Journal Article
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