Source:http://linkedlifedata.com/resource/pubmed/id/11828092
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 2
|
| pubmed:dateCreated |
2002-3-7
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| pubmed:abstractText |
Purple prismatic crystals of the title compound, [Co(2)(C(3)H(6)NS(2))(4)(C(8)H(11)O(2)P)(2)](PF(6))(2), were obtained by repeated recrystallization of trans-[Co(C(3)H(6)NS(2))(2)-(C(8)H(11)O(2)P)(2)]PF(6) from CH(3)CN/Et(2)O and then from MeOH/CH(2)Cl(2); during recrystallization one of the P(OMe)(2)Ph ligands was dissociated from the Co(III) center and the resulting Co(III) complex fragment underwent dimerization. The complex cation has a dinuclear structure bridged by one S atom of each of two of the N,N-dimethyldithiocarbamate ligands, and has crystallographically imposed C(2) symmetry. Two P(OMe)(2)Ph ligands are coordinated at the transoid positions of the Co(2)(mu-C(3)H(6)NS(2))(2)(C(3)H(6)NS(2))(2) moiety, with Co-P bond lengths of 2.1921(11)A.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
58
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m95-7
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| pubmed:dateRevised |
2003-11-3
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| pubmed:year |
2002
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| pubmed:articleTitle |
Bis(mu-N,N-dimethyldithiocarbamato-kappa3S,S':S')bis[(dimethoxyphenylphosphane-kappaP)(N,N-dimethyldithiocarbamato-kappa2S,S')cobalt(III)] bis(hexafluorophosphate).
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| pubmed:affiliation |
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka 560-0043, Japan. suzuki@chem.sci.osaka-u.ac.jp
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| pubmed:publicationType |
Journal Article
|