Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2002-2-4
pubmed:abstractText
The mixed gallium transition-metal complexes [FeCl[Ga(2)((t)Bu)(4)(neol)(2)]] (1) and [M[Ga(2)((t)Bu)(4)(neol)(2)]], M = Co (2), Ni (3), Cu (4), have been prepared by the reaction of [Ga(2)((t)Bu)(4)(neol-H)(2)] (neol-H(2) = 2,2-dimethyl-propane-1,3-diol) with the appropriate metal halide and Proton Sponge. Compounds 1-4 have been characterized by NMR (3), UV/vis, and IR spectroscopy and magnetic susceptibility (solution and solid state), and their molecular structures have been confirmed by X-ray crystallography. The molecular structure of compounds 1-4 consists of a tetracyclic core formed from two four-membered and two six-membered rings. The central metal atom adopts a square pyramidal (1) or square planar (2-4) geometry. The magnetic susceptibilities for 1, 2, and 4 are as expected for strong ligand field environments. On the basis of spectroscopic and structural data, the [Ga(2)((t)Bu)(4)(neol)(2)](2-) ligand appears to be more flexible than other chelating ligands; this is proposed to be due to the flexibility in the O-Ga-O bond angle.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Feb
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
11
pubmed:volume
41
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
571-6
pubmed:dateRevised
2003-11-3
pubmed:year
2002
pubmed:articleTitle
Transition-metal complexes of a bifunctional tetradentate gallium alkoxide ligand.
pubmed:affiliation
Department of Chemistry, Rice University, Houston, Texas 77005, USA.
pubmed:publicationType
Journal Article