Source:http://linkedlifedata.com/resource/pubmed/id/11736515
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
24
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pubmed:dateCreated |
2001-12-13
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pubmed:abstractText |
A new universal scaling law relating the self-diffusivities of a binary fluid mixture and the excess entropies of its components is derived using mode coupling theory, reproducing the empirical scaling laws of Dzugutov [Nature (London) 381, 137 (1996)] and Hoyt et al. [Phys. Rev. Lett. 85, 594 (2000)] as special cases. The derived scaling laws are tested through numerical calculations for binary Lennard-Jones fluid mixtures for a wide range of physical parameters, and a very good correlation is observed. We have also arrived at a new universal scaling relationship between the cross-diffusivity and entropy for the first time.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Dec
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pubmed:issn |
0031-9007
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
10
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pubmed:volume |
87
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
245901
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pubmed:dateRevised |
2004-1-28
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pubmed:year |
2001
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pubmed:articleTitle |
Universal scaling laws of diffusion in a binary fluid mixture.
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pubmed:affiliation |
Theoretical Chemistry Section, RC & CD Division, Chemistry Group, Bhabha Atomic Research Centre, Mumbai 400 085, India.
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pubmed:publicationType |
Journal Article
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