Linked Life Data

11583093

Source:http://linkedlifedata.com/resource/pubmed/id/11583093

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2001-10-3
pubmed:abstractText
A PVC membrane electrode based on a cadmium-salen (N,N'-bis-salicylidene-1,2-ethylenediamine) complex as an anion carrier is described. The electrode has an anti-Hofmeister selectivity sequence with a preference for thiocyanate at pH 1.5-11.0. It has a linear response to thiocyanate from 1.0 x 10(-6) to 1.0 x 10(-1) mol L(-1) with a slope of 59.1 +/- 0.2 mV per decade, and a detection limit of 7 x 10(-7) mol L(-1). This electrode has high selectivity for thiocyanate relative to many common organic and inorganic anions. The proposed sensor has a fast response time of approximately 15 s. It was applied to the determination of thiocyanate in a milk sample.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
0937-0633
pubmed:author
pubmed:issnType
Print
pubmed:volume
370
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1091-5
pubmed:dateRevised
2003-10-31
pubmed:year
2001
pubmed:articleTitle
Highly selective thiocyanate poly(vinyl chloride) membrane electrode based on a cadmium-Schiff's base complex.
pubmed:affiliation
Department of Chemistry, Tehran University, Iran. ganjali@khayam.ut.ac.ir
pubmed:publicationType
Journal Article