Source:http://linkedlifedata.com/resource/pubmed/id/11575779
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
17
|
| pubmed:dateCreated |
2001-9-28
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| pubmed:abstractText |
(Nitrosyl)(salen)ruthenium(II) complex 1 was found to serve as an efficient catalyst for the epoxidation of conjugated olefins under photoirradiation, with 2,6-dichloropyridine N-oxide (2) or tetramethylpyrazine N,N'-dioxide as a stoichiometric oxidant. High enantioselectivity was achieved irrespective of the substitution pattern of olefins. The choice of solvent depends on stability of the resulting epoxides: high enantioselectivity is generally observed in the reaction with ethereal solvents, but use of benzene is recommended when the resulting epoxides are acid-sensitive.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Sep
|
| pubmed:issn |
0947-6539
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
3
|
| pubmed:volume |
7
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
3776-82
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| pubmed:dateRevised |
2009-8-4
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| pubmed:year |
2001
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| pubmed:articleTitle |
Asymmetric epoxidation with a photoactivated [Ru(salen)] complex.
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| pubmed:affiliation |
Department of Chemistry, Faculty of Science, Graduate School, Kyushu University 33, Fukuoka, Japan. katsuscc@mbox.nc.kyushu-u.ac.jp
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| pubmed:publicationType |
Journal Article
|