11574037

Source:http://linkedlifedata.com/resource/pubmed/id/11574037

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Predicate	Object
rdf:type	pubmed:Citation
pubmed:issue	20
pubmed:dateCreated	2001-9-27
pubmed:abstractText	[reaction: see text] The first enantioselective ruthenium olefin metathesis catalysts have been prepared, and high enantiomeric excesses (up to 90%) are observed in the desymmetrization of achiral trienes. A model consistent with the stereochemical outcome of the reactions is described and suggests side-on olefin binding and reorganization of the halide ligands.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Alkenes, http://linkedlifedata.com/resource/pubmed/chemical/Furans, http://linkedlifedata.com/resource/pubmed/chemical/Organometallic Compounds, http://linkedlifedata.com/resource/pubmed/chemical/Ruthenium
pubmed:status	MEDLINE
pubmed:month	Oct
pubmed:issn	1523-7060
pubmed:author	pubmed-author:GrubbsR HRH, pubmed-author:SeidersT JTJ, pubmed-author:WardD WDW
pubmed:issnType	Print
pubmed:day	4
pubmed:volume	3
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3225-8
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:11574037-Alkenes, pubmed-meshheading:11574037-Furans, pubmed-meshheading:11574037-Organometallic Compounds, pubmed-meshheading:11574037-Ruthenium, pubmed-meshheading:11574037-Stereoisomerism
pubmed:year	2001
pubmed:articleTitle	Enantioselective ruthenium-catalyzed ring-closing metathesis.
pubmed:affiliation	Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.
pubmed:publicationType	Journal Article, Research Support, U.S. Gov't, P.H.S.