11574006

Source:http://linkedlifedata.com/resource/pubmed/id/11574006

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0220781, umls-concept:C0439810, umls-concept:C0972306, umls-concept:C1883254
pubmed:issue	20
pubmed:dateCreated	2001-9-27
pubmed:abstractText	[reaction: see text] The enantioselective synthesis of callystatin A is described. The pivotal step in the synthesis is the stereoselective aldol reaction that generates the beta-hydroxy ketone moiety. Utilizing the allylic strain within the ethyl ketone precursor, we were able to generate the all-syn configuration of callystatin A. For the construction of the two diene moieties, both a Heck coupling and a Wittig reaction were employed.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Fatty Acids, Unsaturated, http://linkedlifedata.com/resource/pubmed/chemical/callystatin A
pubmed:status	MEDLINE
pubmed:month	Oct
pubmed:issn	1523-7060
pubmed:author	pubmed-author:KalesseMM, pubmed-author:KhandavalliC PCP, pubmed-author:QuitschalleMM, pubmed-author:SaeedAA
pubmed:issnType	Print
pubmed:day	4
pubmed:volume	3
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3107-9
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:11574006-Animals, pubmed-meshheading:11574006-Fatty Acids, Unsaturated, pubmed-meshheading:11574006-Porifera
pubmed:year	2001
pubmed:articleTitle	Total synthesis of (-)-callystatin A.
pubmed:affiliation	Institut für Organische Chemie, Universität Hannover, Schneiderberg 1B, 30167 Hannover, Germany. kalesse@mbox.oci.uni-hannover.de
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't