Source:http://linkedlifedata.com/resource/pubmed/id/11572685
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
39
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pubmed:dateCreated |
2001-9-26
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pubmed:abstractText |
Interaction of a predesigned molecular "clip" (4) with rigid dipyridyl bridging ligands, in acetone/water mixtures, leads to the formation of molecular rectangles (5-8) in 92-97% isolated yields via spontaneous self-assembly. Characterization was accomplished with multinuclear NMR and UV-vis spectroscopy, FAB mass spectrometry, and X-ray crystallography. The length of these metallamacrocycles ranges from 2 to 3 nm. Postmodification via non-nucleophilic counterion exchange results in enhanced structural integrity for the assemblies.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Oct
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pubmed:issn |
0002-7863
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
3
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pubmed:volume |
123
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
9634-41
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pubmed:dateRevised |
2007-11-14
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pubmed:meshHeading | |
pubmed:year |
2001
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pubmed:articleTitle |
Self-assembly with postmodification: kinetically stabilized metalla-supramolecular rectangles.
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pubmed:affiliation |
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, P.H.S.,
Research Support, U.S. Gov't, Non-P.H.S.
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