rdf:type |
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lifeskim:mentions |
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pubmed:issue |
9
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pubmed:dateCreated |
2001-9-17
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pubmed:abstractText |
The isolation and identification of two pinitol alpha-D-galactosides from jojoba meal are described. The products were isolated by a combination of preparative HPLC on silica gel and TLC on amino silica gel and were identified by MS, NMR spectroscopy, and chemical derivatization as 5-O-(alpha-D-galactopyranosyl)-3-O-methyl-D-chiro-inositol or 5-alpha-D-galactopyranosyl-D-pinitol and 2-O-(alpha-D-galactopyranosyl)-3-O-methyl-D-chiro-inositol or 2-alpha-D-galactopyranosyl-D-pinitol. The same preparative HPLC method on silica gel allowed a new simmondsin derivative to be isolated and identified as 4,5-didemethyl-4-O-alpha-D-glucopyranosylsimmondsin mainly by NMR spectroscopy and high-resolution mass spectrometry.
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pubmed:language |
eng
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pubmed:journal |
|
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Acetonitriles,
http://linkedlifedata.com/resource/pubmed/chemical/Cyclohexanes,
http://linkedlifedata.com/resource/pubmed/chemical/Galactosides,
http://linkedlifedata.com/resource/pubmed/chemical/Glucosides,
http://linkedlifedata.com/resource/pubmed/chemical/Growth Inhibitors,
http://linkedlifedata.com/resource/pubmed/chemical/Inositol,
http://linkedlifedata.com/resource/pubmed/chemical/Silica Gel,
http://linkedlifedata.com/resource/pubmed/chemical/Silicon Dioxide,
http://linkedlifedata.com/resource/pubmed/chemical/Waxes,
http://linkedlifedata.com/resource/pubmed/chemical/jojoba wax,
http://linkedlifedata.com/resource/pubmed/chemical/pinitol,
http://linkedlifedata.com/resource/pubmed/chemical/simmondsin
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pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
0021-8561
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:volume |
49
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4278-83
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pubmed:dateRevised |
2010-11-18
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pubmed:meshHeading |
pubmed-meshheading:11559123-Acetonitriles,
pubmed-meshheading:11559123-Animal Feed,
pubmed-meshheading:11559123-Animals,
pubmed-meshheading:11559123-Chromatography, High Pressure Liquid,
pubmed-meshheading:11559123-Cyclohexanes,
pubmed-meshheading:11559123-Galactosides,
pubmed-meshheading:11559123-Glucosides,
pubmed-meshheading:11559123-Growth Inhibitors,
pubmed-meshheading:11559123-Inositol,
pubmed-meshheading:11559123-Magnetic Resonance Spectroscopy,
pubmed-meshheading:11559123-Mass Spectrometry,
pubmed-meshheading:11559123-Silica Gel,
pubmed-meshheading:11559123-Silicon Dioxide,
pubmed-meshheading:11559123-Waxes
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pubmed:year |
2001
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pubmed:articleTitle |
Identification of 4,5-didemethyl-4-O-alpha-D-glucopyranosylsimmondsin and pinitol alpha-D-galactosides in jojoba seed meal (Simmondsia chinensis).
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pubmed:affiliation |
Laboratory of Toxicology and Food Chemistry, Katholieke Universiteit Leuven, Van Evenstraat 4, B-3000 Leuven, Belgium. maurits.vanboven@farm.kuleuven.ac.be
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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