Linked Life Data

11498625

Source:http://linkedlifedata.com/resource/pubmed/id/11498625

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
Pt 8
pubmed:dateCreated
2001-8-10
pubmed:abstractText
In the title compound, C(4)H(12)N(2)(2+).2C(8)H(7)O(3)(-).2CH(4)O, the cations lie across centres of inversion and are disordered over two orientations with equal occupancy; there are equal numbers of (R)- and (S)-mandelate anions present (mandelate is alpha-hydroxybenzeneacetate). The anions and the neutral water molecules are linked by O-H...O hydrogen bonds [O...O 2.658 (3) and 2.682 (3) A, and O-H...O 176 and 166 degrees] into deeply folded zigzag chains. Each orientation of the cation forms two symmetry-related two-centre N-H...O hydrogen bonds [N...O 2.588 (4) and 2.678 (4) A, and N-H...O 177 and 171 degrees] and two asymmetric, but planar, three-centre N-H...(O)(2) hydrogen bonds [N...O 2.686 (4)-3.137 (4) A and N-H...O 137-147 degrees], and by means of these the cations link the anion/water chains into bilayers.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
0108-2701
pubmed:author
pubmed:issnType
Print
pubmed:volume
57
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
955-7
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2001
pubmed:articleTitle
Hydrogen-bonded bilayers in piperazinium(2+) bis(mandelate) bis(methanol) solvate.
pubmed:affiliation
School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, Scotland.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't