Source:http://linkedlifedata.com/resource/pubmed/id/11486952
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
13
|
| pubmed:dateCreated |
2001-8-6
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| pubmed:abstractText |
Reaction of divalent hexacoordinate metal ions with either tetradentate N-(2-piridylmethyl)iminodiethanol (3; H2L4) or tridentate N-(2-chlorobenzyl)iminodiethanol (5; H2L5) resulted in the formation of two completely different products. Starting from nickel(II) acetate and tetradentate 3, linear trinuclear complex [[Ni(HL4)]2-Ni(OAc)2(HCO2)2] (4) was formed. However, when tridentate 5 was allowed to react with cobalt(II) acetate, the novel octadecametallic square box [Na2-(Co4(HL5)3(OAc)5]4(HCO2)2] (6) was isolated. Chiral 6 has D2-molecule symmetry and crystalizes with both enantiomers in the unit cell. The structures of all new compounds were determined unequivocally by single-crystal X-ray analyses.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jul
|
| pubmed:issn |
0947-6539
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
2
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| pubmed:volume |
7
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
2770-4
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| pubmed:dateRevised |
2009-8-4
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| pubmed:year |
2001
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| pubmed:articleTitle |
Self-assembly and crystal structure of a novel octadecametallic square box composed of 52 single components.
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| pubmed:affiliation |
Institut für Organische Chemie der Universität Erlangen-Nürnberg, Germany. saalfrank@organik.uni-erlangen.de
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| pubmed:publicationType |
Journal Article
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