Source:http://linkedlifedata.com/resource/pubmed/id/11418038
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
13
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| pubmed:dateCreated |
2001-6-21
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| pubmed:abstractText |
[reaction: see text] BF(3)-promoted 1,4-addition of bulky aryl groups to alpha-iodo enones, prepared from the parent enones, afforded beta-aryl-alpha-iodo ketones. Subsequent reaction with EtMgBr furnished the magnesium enolates, which upon reactions with ClP(O)(OEt)(2) and aldehydes gave enol phosphates and aldols, respectively. This method was applied successfully to a synthesis of Delta(1)-trans-tetrahydrocannabinol.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
1523-7060
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
28
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| pubmed:volume |
3
|
| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
2017-20
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| pubmed:dateRevised |
2003-10-31
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| pubmed:year |
2001
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| pubmed:articleTitle |
A method to accomplish a 1,4-addition reaction of bulky nucleophiles to enones and subsequent formation of reactive enolates.
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| pubmed:affiliation |
Department of Biomolecular Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan.
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| pubmed:publicationType |
Journal Article
|