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pubmed-article:11263912pubmed:abstractTextA novel route to epoxysorbicillinol as well as dimers of sorbicillin is reported. The synthesis is-in principle-amenable to enantioselectivity. The key step is an oxidative dearomatization to produce a stable and highly malleable p-quinol intermediate, which undergoes a highly diastereoselective epoxidation.lld:pubmed
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pubmed-article:11263912pubmed:articleTitleSynthesis of (+/-)-epoxysorbicillinol using a novel cyclohexa-2,5-dienone with synthetic applications to other sorbicillin derivatives.lld:pubmed
pubmed-article:11263912pubmed:affiliationDepartment of Chemistry and Biochemistry, University of California at Santa Barbara, Santa Barbara, California 93106, USA. pettus@chem.ucsb.edulld:pubmed
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