Source:http://linkedlifedata.com/resource/pubmed/id/11249107
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
4
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pubmed:dateCreated |
2001-3-15
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pubmed:abstractText |
The absolute configuration of (+)-isoshinanolone, a wide-spread acetogenic metabolite from higher plants, has been determined by X-ray structure analysis of its new dibromide; accordingly, this natural tetralone is 3R,4R-configured, in agreement with previous degradative results. In addition, a first chiroptical on-line stereoanalysis for isoshinanolones is presented, i.a. by HPLC on a chiral phase coupled to CD spectroscopy, giving pure CD spectra of all of the four stereoisomers of isoshinanolone directly from stereoisomeric mixtures.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
0031-9422
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
56
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
387-91
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:11249107-Chromatography, High Pressure Liquid,
pubmed-meshheading:11249107-Circular Dichroism,
pubmed-meshheading:11249107-Crystallography, X-Ray,
pubmed-meshheading:11249107-Magnetic Resonance Spectroscopy,
pubmed-meshheading:11249107-Molecular Conformation,
pubmed-meshheading:11249107-Plant Extracts,
pubmed-meshheading:11249107-Plants,
pubmed-meshheading:11249107-Stereoisomerism,
pubmed-meshheading:11249107-Tetrahydronaphthalenes
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pubmed:year |
2001
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pubmed:articleTitle |
The absolute configuration of (+)-isoshinanolone and in situ LC-CD analysis of its stereoisomers from crude extracts.
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pubmed:affiliation |
Institut fur Organische Chemie der Universität, Am Hubland, Würzburg, Germany. bringman@chemie.uni-wuerzburg.de
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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