Source:http://linkedlifedata.com/resource/pubmed/id/11196832
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
16
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| pubmed:dateCreated |
2001-1-24
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| pubmed:abstractText |
Two intramolecular stabilized arylaluminum dihydrides, (2-(NEt2CH2)-6-MeC6H3)AlH2 (1) and (2,6-(NEt2CH2)2C6H3)AlH2 (2), were prepared by reducing the corresponding dichlorides with an excess of LiAlH4 in diethyl ether. Reactions of 1 and 2 with elemental selenium afforded the dimeric arylaluminum selenides [(2-(NEt2CH2)-6-MeC6H3)AlSe]2 (3) and [(2,6-(NEt2CH2)2C6H3)AlSe]2 (4). Reaction of 2 with metallic tellurium gave the dimeric arylaluminum telluride [(2,6-(NEt2CH2)2C6H3)AlTe]2 (5). The possible reaction pathway is discussed, and molecular structures determined by single-crystal X-ray analyses are presented for 3 and 5.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
39
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
3678-81
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| pubmed:dateRevised |
2003-10-31
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| pubmed:articleTitle |
Syntheses and structures of the arylaluminum chalcogenides (ArAlE)2 (Ar = 2-(NEt2CH2)-6-MeC6H3, E = Se; Ar = 2,6-(NEt2CH2)2C6H3, E = Se, Te).
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| pubmed:affiliation |
Institute of Inorganic Chemistry, University of Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
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| pubmed:publicationType |
Journal Article
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