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pubmed-article:11178818pubmed:abstractText[reaction: see text] The kinetic resolution of racemic allylic alcohols 3, 6, and 12--17 has been explored using the PBO catalyst 7 for activation of isobutyric anhydride. Trisubstituted allylic alcohols (12--15; 17) are the best substrates and react with an enantioselectivity of s = 32--82 at -40 degrees C.lld:pubmed
pubmed-article:11178818pubmed:languageenglld:pubmed
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pubmed-article:11178818pubmed:issn1523-7060lld:pubmed
pubmed-article:11178818pubmed:authorpubmed-author:VedejsEElld:pubmed
pubmed-article:11178818pubmed:authorpubmed-author:MacKayJ AJAlld:pubmed
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pubmed-article:11178818pubmed:pagination535-6lld:pubmed
pubmed-article:11178818pubmed:dateRevised2003-10-31lld:pubmed
pubmed-article:11178818pubmed:year2001lld:pubmed
pubmed-article:11178818pubmed:articleTitleKinetic resolution of allylic alcohols using a chiral phosphine catalyst.lld:pubmed
pubmed-article:11178818pubmed:affiliationDepartment of Chemistry, University of Michigan, Ann Arbor 48109, USA. edved@umich.edulld:pubmed
pubmed-article:11178818pubmed:publicationTypeJournal Articlelld:pubmed
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