11178818

Source:http://linkedlifedata.com/resource/pubmed/id/11178818

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0051225, umls-concept:C0070813, umls-concept:C0175921, umls-concept:C2699488
pubmed:issue	4
pubmed:dateCreated	2001-2-22
pubmed:abstractText	[reaction: see text] The kinetic resolution of racemic allylic alcohols 3, 6, and 12--17 has been explored using the PBO catalyst 7 for activation of isobutyric anhydride. Trisubstituted allylic alcohols (12--15; 17) are the best substrates and react with an enantioselectivity of s = 32--82 at -40 degrees C.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Feb
pubmed:issn	1523-7060
pubmed:author	pubmed-author:MacKayJ AJA, pubmed-author:VedejsEE
pubmed:issnType	Print
pubmed:day	22
pubmed:volume	3
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	535-6
pubmed:dateRevised	2003-10-31
pubmed:year	2001
pubmed:articleTitle	Kinetic resolution of allylic alcohols using a chiral phosphine catalyst.
pubmed:affiliation	Department of Chemistry, University of Michigan, Ann Arbor 48109, USA. edved@umich.edu
pubmed:publicationType	Journal Article