Linked Life Data

11151493

Source:http://linkedlifedata.com/resource/pubmed/id/11151493

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
26
pubmed:dateCreated
2001-1-9
pubmed:abstractText
A series of cyclic metalloporphyrin trimers, Ru(CO)(py)[Sn(carboxylate)2](2)2, having cavities lined with different carboxylate groups are synthesized by adding the appropriate carboxylic acids to the mixed trimer Ru(CO)(py)-[Sn(OH)2](2)2. This methodology provides ready access to a wide range of cavities lined with substituents possessing chirality or hydrogen-bonding groups. The potential of such systems is illustrated by synergistic binding of a hydroxypyridine to the Ru(II)-CO center and to the hydroxyl groups of a D-quinate-lined cavity. The effect of changing the carboxylate lining of the cavity on the course of epoxidation reactions catalyzed by these trimers is also reported.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Dec
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
25
pubmed:volume
39
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5920-9
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2000
pubmed:articleTitle
A tin(IV)-ruthenium(II)-tin(IV) cyclic porphyrin trimer with replaceable chiral linings.
pubmed:affiliation
Department of Chemistry, University of Sheffield, Sheffield S3 7HF, U.K. S.J.Webb@sheffield.ac.uk
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't