Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2001-1-3
pubmed:abstractText
A series of ZnII and CdII complexes of adenine and guanine derivatives containing a diamine tether have been isolated from aqueous solutions and characterised by single crystal X-ray analysis. These studies reveal a wide range of structural types including monomeric, dimeric, tetrameric and polymeric architectures. The extended structures arise from the ability of the ligands to bridge metal ions using the chelating tether in conjunction with N7 of the nucleobase. Additional metal-nucleobase co-ordination is generally observed at the N3-site of the adenine derivatives. With CdII, ethylenediamine-N9-ethylguanine forms an inverted G-tetrad type structure.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Dec
pubmed:issn
0947-6539
pubmed:author
pubmed:issnType
Print
pubmed:day
1
pubmed:volume
6
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4371-8
pubmed:dateRevised
2009-8-4
pubmed:year
2000
pubmed:articleTitle
Monomer, dimer, tetramer, polymer: structural diversity in zinc and cadmium complexes of chelate-tethered nucleobases.
pubmed:affiliation
Department of Chemistry, University of Newcastle upon Tyne, UK.
pubmed:publicationType
Journal Article