10836048

Source:http://linkedlifedata.com/resource/pubmed/id/10836048

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0009264, umls-concept:C0043393, umls-concept:C0238749, umls-concept:C0301630
pubmed:issue	12
pubmed:dateCreated	2000-7-17
pubmed:abstractText	[formula: see text] The bakers' yeast mediated reduction of 3-oxo-3-phenylpropanenitrile (1) proceeds at 4 degrees C to give exclusively (S)-3-hydroxy-3-phenylpropanenitrile (3) in 59% yield. This is in contrast to the corresponding reaction at room temperature which yields a mixture of reduction and alkylation products. This work demonstrates the use of low temperature to improve yeast selectivity.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Nitriles
pubmed:status	MEDLINE
pubmed:month	Dec
pubmed:issn	1523-7060
pubmed:author	pubmed-author:FloresZZ, pubmed-author:SmallridgeA JAJ, pubmed-author:TrewhellaM AMA, pubmed-author:UGOAA
pubmed:issnType	Print
pubmed:day	16
pubmed:volume	1
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1879-80
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:10836048-Alkylation, pubmed-meshheading:10836048-Nitriles, pubmed-meshheading:10836048-Oxidation-Reduction, pubmed-meshheading:10836048-Saccharomyces cerevisiae, pubmed-meshheading:10836048-Stereoisomerism
pubmed:year	1999
pubmed:articleTitle	Chemo- and stereoselective reduction of an alpha-cyanoketone by bakers' yeast at low temperature.
pubmed:affiliation	School of Life Sciences and Technology, Victoria University of Technology, Melbourne City, Australia.
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't