Linked Life Data

10677087

Source:http://linkedlifedata.com/resource/pubmed/id/10677087

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2000-2-25
pubmed:abstractText
The combination of cathodic amperometric detection with capillary zone electrophoresis is demonstrated to be a versatile method for the quantification of organic and inorganic peroxides. A gold microelectrode, polarized at -600 mV against an Ag/AgCl reference electrode, is placed at the end of the capillary. Since the electroosmotic flow purges the detector electrode from oxygen, no degassing of the detector cell or the sample is necessary. With an injection volume of ca. 1 nl, hydrogen peroxide, peroxosulfate, peroxy alkanoic acids and the hydroperoxides of linoleic acid can be detected down to 10 micromol/l. Separation of the isomeric hydroperoxides of the unsaturated fatty acids is achieved by addition of beta-cyclodextrin to the electrolyte.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
0021-9673
pubmed:author
pubmed:issnType
Print
pubmed:day
28
pubmed:volume
868
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
127-34
pubmed:dateRevised
2009-1-15
pubmed:meshHeading
pubmed:year
2000
pubmed:articleTitle
Determination of peroxides by capillary zone electrophoresis with amperometric detection.
pubmed:affiliation
Institute of Pharmaceutical Chemistry, Department of Pharmacy, Martin-Luther-University, Halle, Germany.
pubmed:publicationType
Journal Article