9,12-octadecadienoate 8-hydroperoxide 8S-isomerase

The bifunctional enzyme from Gaeumannomyces graminis catalyzes the oxidation of linoleic acid to (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate (cf. EC 1.13.11.60), which is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxyoctadeca-9,12-dienoate.

Source:http://purl.uniprot.org/enzyme/5.4.4.6

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