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pubmed-article:7159680pubmed:abstractTextThe concentration-dependent mixed association behavior of cholesterol with methyl cholate (MeC) and methyl lithocholate (MeLC) in chloroform at 37 degrees C has been studied by vapor pressure osmometry (VPO). This study is part of a larger project to investigate the effect of number and position of hydroxyl-bearing steroids. Using theories developed by Adams and by Steiner, the model and appropriate parameters for the nonideal mixed associations were elucidated. For the MeLC/cholesterol system, no mixed association was observed. For the MeC/cholesterol system, both methods of analysis indicate that a nonideal AB complex formation occurs. The best parameters to explain the experimental data are kAB = 0.04 1/g; BAB (the nonideal term) = 1.5 X 10(-5) 1 mol g-2.lld:pubmed
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pubmed-article:7159680pubmed:authorpubmed-author:RobesonJJlld:pubmed
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pubmed-article:7159680pubmed:dateRevised2008-11-21lld:pubmed
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pubmed-article:7159680pubmed:articleTitleMixed association of cholesterol with methyl cholate and methyl lithocholate in chloroform solutions.lld:pubmed
pubmed-article:7159680pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:7159680pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed
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