| pubmed-article:6592593 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:6592593 | lifeskim:mentions | umls-concept:C0038317 | lld:lifeskim |
| pubmed-article:6592593 | lifeskim:mentions | umls-concept:C0444626 | lld:lifeskim |
| pubmed-article:6592593 | lifeskim:mentions | umls-concept:C0022203 | lld:lifeskim |
| pubmed-article:6592593 | lifeskim:mentions | umls-concept:C2934345 | lld:lifeskim |
| pubmed-article:6592593 | lifeskim:mentions | umls-concept:C0639597 | lld:lifeskim |
| pubmed-article:6592593 | pubmed:issue | 18 | lld:pubmed |
| pubmed-article:6592593 | pubmed:dateCreated | 1984-11-5 | lld:pubmed |
| pubmed-article:6592593 | pubmed:abstractText | The influence of configuration at C-20 on rotation about the 17(20)-bond in steroids and euphoids was examined by x-ray crystallographic studies of the C-20 epimers euphol and tirucallol. The H atom on C-20 was in back next to C-18 in the crystal structures of both of the compounds, and C-22 was found to be cis-oriented ("left-handed") to C-13 in euphol and trans-oriented to it ("right-handed") in tirucallol. The results, which are consistent with the known left-handed crystal structure of 24(25)-dihydroeuphol and right-handed crystal structure of cholesterol and other natural sterols, lend further credence to the earlier suggestion that rotational isomerism at the 17(20)-bond can arise in C-20 epimers and that there is preference for an arrangement with the 20-H atom adjacent to C-18. | lld:pubmed |
| pubmed-article:6592593 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
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| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
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| pubmed-article:6592593 | pubmed:language | eng | lld:pubmed |
| pubmed-article:6592593 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:6592593 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:6592593 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:6592593 | pubmed:month | Sep | lld:pubmed |
| pubmed-article:6592593 | pubmed:issn | 0027-8424 | lld:pubmed |
| pubmed-article:6592593 | pubmed:author | pubmed-author:LandreyJ RJR | lld:pubmed |
| pubmed-article:6592593 | pubmed:author | pubmed-author:BensonMM | lld:pubmed |
| pubmed-article:6592593 | pubmed:author | pubmed-author:RaoS TST | lld:pubmed |
| pubmed-article:6592593 | pubmed:author | pubmed-author:RaoS BSB | lld:pubmed |
| pubmed-article:6592593 | pubmed:author | pubmed-author:WongR YRY | lld:pubmed |
| pubmed-article:6592593 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:6592593 | pubmed:volume | 81 | lld:pubmed |
| pubmed-article:6592593 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:6592593 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:6592593 | pubmed:pagination | 5896-900 | lld:pubmed |
| pubmed-article:6592593 | pubmed:dateRevised | 2010-9-10 | lld:pubmed |
| pubmed-article:6592593 | pubmed:meshHeading | pubmed-meshheading:6592593-... | lld:pubmed |
| pubmed-article:6592593 | pubmed:meshHeading | pubmed-meshheading:6592593-... | lld:pubmed |
| pubmed-article:6592593 | pubmed:meshHeading | pubmed-meshheading:6592593-... | lld:pubmed |
| pubmed-article:6592593 | pubmed:meshHeading | pubmed-meshheading:6592593-... | lld:pubmed |
| pubmed-article:6592593 | pubmed:meshHeading | pubmed-meshheading:6592593-... | lld:pubmed |
| pubmed-article:6592593 | pubmed:year | 1984 | lld:pubmed |
| pubmed-article:6592593 | pubmed:articleTitle | Rotational isomerism about the 17(20)-bond of steroids and euphoids as shown by the crystal structures of euphol and tirucallol. | lld:pubmed |
| pubmed-article:6592593 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:6592593 | pubmed:publicationType | Comparative Study | lld:pubmed |
| pubmed-article:6592593 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:6592593 | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:6592593 | lld:pubmed |
