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pubmed-article:3185115pubmed:abstractTextMalondialdehyde (MA) formed in linolenic acid, linoleic acid, corn oil and beef fat upon photoirradiation was determined by gas chromatography (GC). The MA produced was reacted with methylhydrazine to give 1-methylpyrazole and was subsequently analyzed on a GC equipped with a nitrogen-phosphorus specific detector and a fused silica capillary column. MA values determined by this method correspond to free or unbound MA levels. Linolenic and linoleic acids produced 867 micrograms MA/g and 106 micrograms MA/g, respectively. Oleic and stearic acids did not produce detectable levels of MA upon photoirradiation. Amounts of MA produced after eight hour irradiations of corn oil and beef fat were 56.24 micrograms/g and 25.01 micrograms/g, respectively. Some photoreaction products in irradiated corn oil also were identified as methylhydrazine derivatives.lld:pubmed
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pubmed-article:3185115pubmed:authorpubmed-author:DennisK JKJlld:pubmed
pubmed-article:3185115pubmed:authorpubmed-author:ShibamotoTTlld:pubmed
pubmed-article:3185115pubmed:authorpubmed-author:UmanoKKlld:pubmed
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pubmed-article:3185115pubmed:volume23lld:pubmed
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pubmed-article:3185115pubmed:pagination811-4lld:pubmed
pubmed-article:3185115pubmed:dateRevised2007-11-14lld:pubmed
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pubmed-article:3185115pubmed:articleTitleAnalysis of free malondialdehyde in photoirradiated corn oil and beef fat via a pyrazole derivative.lld:pubmed
pubmed-article:3185115pubmed:affiliationDepartment of Environmental Toxicology, University of California, Davis 95616.lld:pubmed
pubmed-article:3185115pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:3185115pubmed:publicationTypeComparative Studylld:pubmed
pubmed-article:3185115pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed