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pubmed-article:21337078rdf:typepubmed:Citationlld:pubmed
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pubmed-article:21337078pubmed:dateCreated2011-2-21lld:pubmed
pubmed-article:21337078pubmed:abstractTextIn this work we investigate the influence of the adsorption of ions on the impedance spectroscopy of an electrolytic cell. We consider that the positive and negative ions present in a dielectric liquid are adsorbed in the electrode surfaces with different adsorption energies. This difference in adsorption energies causes an additional plateaux in the limit of the low-frequency range of the real part of the impedance Z. In the same frequency range, a second minimum in the imaginary part of Z is predicted. The theory is illustrated with measurements of the impedance of an electrolytic solution in the frequency range from 10(-2) Hz to 1 KHz. A comparison between the present model and others from the literature to describe the experimental results is also made.lld:pubmed
pubmed-article:21337078pubmed:languageenglld:pubmed
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pubmed-article:21337078pubmed:issn1292-895Xlld:pubmed
pubmed-article:21337078pubmed:authorpubmed-author:DuarteA RARlld:pubmed
pubmed-article:21337078pubmed:authorpubmed-author:Figueiredo...lld:pubmed
pubmed-article:21337078pubmed:authorpubmed-author:MartinsO GOGlld:pubmed
pubmed-article:21337078pubmed:authorpubmed-author:BataliotoFFlld:pubmed
pubmed-article:21337078pubmed:issnTypeElectroniclld:pubmed
pubmed-article:21337078pubmed:volume34lld:pubmed
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pubmed-article:21337078pubmed:year2011lld:pubmed
pubmed-article:21337078pubmed:articleTitleThe influence of adsorption phenomena on the impedance spectroscopy of an electrolytic cell.lld:pubmed
pubmed-article:21337078pubmed:affiliationInstituto de Física, Universidade de São Paulo, P.O. Box 66318, 05314-970, SP-Brazil. f_batalioto@yahoo.com.brlld:pubmed
pubmed-article:21337078pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21337078pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed