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pubmed-article:21280606rdf:typepubmed:Citationlld:pubmed
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pubmed-article:21280606pubmed:issue7lld:pubmed
pubmed-article:21280606pubmed:dateCreated2011-2-17lld:pubmed
pubmed-article:21280606pubmed:abstractTextWe demonstrate fast characterization of the distribution of surface bonding modes and interactions in a series of functionalized materials via surface-enhanced nuclear magnetic resonance spectroscopy using dynamic nuclear polarization (DNP). Surface-enhanced silicon-29 DNP NMR spectra were obtained by using incipient wetness impregnation of the sample with a solution containing a polarizing radical (TOTAPOL). We identify and compare the bonding topology of functional groups in materials obtained via a sol-gel process and in materials prepared by post-grafting reactions. Furthermore, the remarkable gain in time provided by surface-enhanced silicon-29 DNP NMR spectroscopy (typically on the order of a factor 400) allows the facile acquisition of two-dimensional correlation spectra.lld:pubmed
pubmed-article:21280606pubmed:languageenglld:pubmed
pubmed-article:21280606pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:21280606pubmed:statusPubMed-not-MEDLINElld:pubmed
pubmed-article:21280606pubmed:monthFeblld:pubmed
pubmed-article:21280606pubmed:issn1520-5126lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:EmsleyLyndonLlld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:BodenhausenGe...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:LelliMorenoMlld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:VeyreLaurentLlld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:LesageAnneAlld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:CopéretChrist...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:CaporiniMarc...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:ThieuleuxChlo...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:GajanDavidDlld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:BouallegMalik...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:VitzthumVeron...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:MiévillePasca...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:RousseyArthur...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:HéroguelFlore...lld:pubmed
pubmed-article:21280606pubmed:authorpubmed-author:RascónFernand...lld:pubmed
pubmed-article:21280606pubmed:issnTypeElectroniclld:pubmed
pubmed-article:21280606pubmed:day23lld:pubmed
pubmed-article:21280606pubmed:volume133lld:pubmed
pubmed-article:21280606pubmed:ownerNLMlld:pubmed
pubmed-article:21280606pubmed:authorsCompleteYlld:pubmed
pubmed-article:21280606pubmed:pagination2104-7lld:pubmed
pubmed-article:21280606pubmed:year2011lld:pubmed
pubmed-article:21280606pubmed:articleTitleFast characterization of functionalized silica materials by silicon-29 surface-enhanced NMR spectroscopy using dynamic nuclear polarization.lld:pubmed
pubmed-article:21280606pubmed:affiliationCentre de RMN a? Tre?s Hauts Champs, Universite? de Lyon (CNRS/ENS Lyon/UCB Lyon 1), 69100 Villeurbanne, France.lld:pubmed
pubmed-article:21280606pubmed:publicationTypeJournal Articlelld:pubmed