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pubmed-article:21079821pubmed:abstractTextReactions of Re(V), tetradentate Schiff base complexes with tertiary phosphines have previously yielded both rearranged Re(V) and reduced Re(III) complexes. To further understand this chemistry, the rigid diiminediphenol (N(2)O(2)) Schiff base ligand sal(2)phen (N,N'-o-phenylenebis(salicylaldimine)) was reacted with (n-Bu(4)N)[ReOCl(4)] to yield trans-[ReOCl(sal(2)phen)] (1). On reaction with triphenylphosphine (PPh(3)), a rearranged Re(V) product cis-[ReO(PPh(3))(sal(2)phen*)]PF(6) (2), in which one of the imines was reduced to an amine during the reaction, and the reduced Re(III) products trans-[ReCl(PPh(3))(sal(2)phen)] (4) and trans-[Re(PPh(3))(2)(sal(2)phen)](+) (5) were isolated. Reaction of sal(2)phen with [ReCl(3)(PPh(3))(2)(CH(3)CN)] resulted in the isolation of [ReCl(2)(PPh(3))(2)(salphen)] (3). The compounds were characterized using standard spectroscopic methods, elemental analyses and single crystal X-ray crystallography.lld:pubmed
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pubmed-article:21079821pubmed:dateRevised2011-9-26lld:pubmed
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pubmed-article:21079821pubmed:year2011lld:pubmed
pubmed-article:21079821pubmed:articleTitleRe(V) and Re(III) complexes with sal2phen and triphenylphosphine: rearrangement, oxidation and reduction.lld:pubmed
pubmed-article:21079821pubmed:affiliationDepartment of Chemistry, University of Missouri-Columbia, Columbia, MO 65211, USA.lld:pubmed
pubmed-article:21079821pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21079821pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
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