Statements in which the resource exists.
SubjectPredicateObjectContext
pubmed-article:20865804rdf:typepubmed:Citationlld:pubmed
pubmed-article:20865804lifeskim:mentionsumls-concept:C0018026lld:lifeskim
pubmed-article:20865804lifeskim:mentionsumls-concept:C0205148lld:lifeskim
pubmed-article:20865804lifeskim:mentionsumls-concept:C0332621lld:lifeskim
pubmed-article:20865804lifeskim:mentionsumls-concept:C0024483lld:lifeskim
pubmed-article:20865804lifeskim:mentionsumls-concept:C0205431lld:lifeskim
pubmed-article:20865804pubmed:dateCreated2011-3-22lld:pubmed
pubmed-article:20865804pubmed:abstractTextThe spontaneous ordering of molecules into two-dimensional self-assembled arrays is commonly stabilized by directional intermolecular interactions that may be promoted by the addition of specific chemical side groups to a molecule. In this paper, we show that self-assembly may also be driven by anisotropic interactions that arise from the three-dimensional shape of a complex molecule. We study the molecule Mn(12)O(12)(O(2)CCH(3))(16)(H(2)O)(4) (Mn(12)(acetate)(16)), which is transferred from solution onto a Au(111) substrate held in ultrahigh vacuum using electrospray deposition (UHV-ESD). The deposited Mn(12)(acetate)(16) molecules form filamentary aggregates because of the anisotropic nature of the molecule-molecule and molecule-substrate interactions, as confirmed by molecular dynamics calculations. The fragile Mn(12)O(12) core of the Mn(12)(acetate)(16) molecule is compatible with the UHV-ESD process, which we demonstrate using near-edge X-ray adsorption fine-structure spectroscopy. UHV-ESD of Mn(12)(acetate)(16) onto a surface that has been prepatterned with a hydrogen-bonded supramolecular network provides additional control of lateral organization.lld:pubmed
pubmed-article:20865804pubmed:languageenglld:pubmed
pubmed-article:20865804pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:20865804pubmed:citationSubsetIMlld:pubmed
pubmed-article:20865804pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:20865804pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:20865804pubmed:statusMEDLINElld:pubmed
pubmed-article:20865804pubmed:issn2041-1723lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:ChampnessNeil...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:O'SheaJames...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:BetonPeter...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:PerdigãoLuís...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:SatterleyChri...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:SaywellAlexAlld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:MagnanoGrazia...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:BrittonAndrew...lld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:TalebNassibaNlld:pubmed
pubmed-article:20865804pubmed:authorpubmed-author:del Carmen...lld:pubmed
pubmed-article:20865804pubmed:issnTypeElectroniclld:pubmed
pubmed-article:20865804pubmed:volume1lld:pubmed
pubmed-article:20865804pubmed:ownerNLMlld:pubmed
pubmed-article:20865804pubmed:authorsCompleteYlld:pubmed
pubmed-article:20865804pubmed:pagination75lld:pubmed
pubmed-article:20865804pubmed:meshHeadingpubmed-meshheading:20865804...lld:pubmed
pubmed-article:20865804pubmed:meshHeadingpubmed-meshheading:20865804...lld:pubmed
pubmed-article:20865804pubmed:meshHeadingpubmed-meshheading:20865804...lld:pubmed
pubmed-article:20865804pubmed:meshHeadingpubmed-meshheading:20865804...lld:pubmed
pubmed-article:20865804pubmed:meshHeadingpubmed-meshheading:20865804...lld:pubmed
pubmed-article:20865804pubmed:year2010lld:pubmed
pubmed-article:20865804pubmed:articleTitleSelf-assembled aggregates formed by single-molecule magnets on a gold surface.lld:pubmed
pubmed-article:20865804pubmed:affiliationSchool of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD, UK.lld:pubmed
pubmed-article:20865804pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:20865804pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed