pubmed-article:20865804 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:20865804 | lifeskim:mentions | umls-concept:C0018026 | lld:lifeskim |
pubmed-article:20865804 | lifeskim:mentions | umls-concept:C0205148 | lld:lifeskim |
pubmed-article:20865804 | lifeskim:mentions | umls-concept:C0332621 | lld:lifeskim |
pubmed-article:20865804 | lifeskim:mentions | umls-concept:C0024483 | lld:lifeskim |
pubmed-article:20865804 | lifeskim:mentions | umls-concept:C0205431 | lld:lifeskim |
pubmed-article:20865804 | pubmed:dateCreated | 2011-3-22 | lld:pubmed |
pubmed-article:20865804 | pubmed:abstractText | The spontaneous ordering of molecules into two-dimensional self-assembled arrays is commonly stabilized by directional intermolecular interactions that may be promoted by the addition of specific chemical side groups to a molecule. In this paper, we show that self-assembly may also be driven by anisotropic interactions that arise from the three-dimensional shape of a complex molecule. We study the molecule Mn(12)O(12)(O(2)CCH(3))(16)(H(2)O)(4) (Mn(12)(acetate)(16)), which is transferred from solution onto a Au(111) substrate held in ultrahigh vacuum using electrospray deposition (UHV-ESD). The deposited Mn(12)(acetate)(16) molecules form filamentary aggregates because of the anisotropic nature of the molecule-molecule and molecule-substrate interactions, as confirmed by molecular dynamics calculations. The fragile Mn(12)O(12) core of the Mn(12)(acetate)(16) molecule is compatible with the UHV-ESD process, which we demonstrate using near-edge X-ray adsorption fine-structure spectroscopy. UHV-ESD of Mn(12)(acetate)(16) onto a surface that has been prepatterned with a hydrogen-bonded supramolecular network provides additional control of lateral organization. | lld:pubmed |
pubmed-article:20865804 | pubmed:language | eng | lld:pubmed |
pubmed-article:20865804 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:20865804 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:20865804 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:20865804 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:20865804 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:20865804 | pubmed:issn | 2041-1723 | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:ChampnessNeil... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:O'SheaJames... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:BetonPeter... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:PerdigãoLuís... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:SatterleyChri... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:SaywellAlexA | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:MagnanoGrazia... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:BrittonAndrew... | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:TalebNassibaN | lld:pubmed |
pubmed-article:20865804 | pubmed:author | pubmed-author:del Carmen... | lld:pubmed |
pubmed-article:20865804 | pubmed:issnType | Electronic | lld:pubmed |
pubmed-article:20865804 | pubmed:volume | 1 | lld:pubmed |
pubmed-article:20865804 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:20865804 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:20865804 | pubmed:pagination | 75 | lld:pubmed |
pubmed-article:20865804 | pubmed:meshHeading | pubmed-meshheading:20865804... | lld:pubmed |
pubmed-article:20865804 | pubmed:meshHeading | pubmed-meshheading:20865804... | lld:pubmed |
pubmed-article:20865804 | pubmed:meshHeading | pubmed-meshheading:20865804... | lld:pubmed |
pubmed-article:20865804 | pubmed:meshHeading | pubmed-meshheading:20865804... | lld:pubmed |
pubmed-article:20865804 | pubmed:meshHeading | pubmed-meshheading:20865804... | lld:pubmed |
pubmed-article:20865804 | pubmed:year | 2010 | lld:pubmed |
pubmed-article:20865804 | pubmed:articleTitle | Self-assembled aggregates formed by single-molecule magnets on a gold surface. | lld:pubmed |
pubmed-article:20865804 | pubmed:affiliation | School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD, UK. | lld:pubmed |
pubmed-article:20865804 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:20865804 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |