| pubmed-article:20666410 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C0030011 | lld:lifeskim |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C1704241 | lld:lifeskim |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C0441712 | lld:lifeskim |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C0682927 | lld:lifeskim |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C0215830 | lld:lifeskim |
| pubmed-article:20666410 | lifeskim:mentions | umls-concept:C2347052 | lld:lifeskim |
| pubmed-article:20666410 | pubmed:issue | 32 | lld:pubmed |
| pubmed-article:20666410 | pubmed:dateCreated | 2010-8-11 | lld:pubmed |
| pubmed-article:20666410 | pubmed:abstractText | The experiments described here clarify the mechanism and origin of the enantioselectivity of the oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes using HOBr, Br(2)/H(2)O/KOAc or PhI(OAc)(2)/H(2)O/KBr as a stoichiometric oxidant. Key points of the proposed pathway include (1) the formation of a Mn(V)-salen dibromide, (2) its subsequent reaction with the alcohol to give an alkoxy-Mn(V) species, and (3) carbonyl-forming elimination to produce the ketone via a highly organized transition state with intramolecular transfer of hydrogen from carbon to an oxygen of the salen ligand. | lld:pubmed |
| pubmed-article:20666410 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:language | eng | lld:pubmed |
| pubmed-article:20666410 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:20666410 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
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| pubmed-article:20666410 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20666410 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:20666410 | pubmed:month | Aug | lld:pubmed |
| pubmed-article:20666410 | pubmed:issn | 1520-5126 | lld:pubmed |
| pubmed-article:20666410 | pubmed:author | pubmed-author:CoreyE JEJ | lld:pubmed |
| pubmed-article:20666410 | pubmed:author | pubmed-author:BrownM... | lld:pubmed |
| pubmed-article:20666410 | pubmed:author | pubmed-author:BlewettMegan... | lld:pubmed |
| pubmed-article:20666410 | pubmed:author | pubmed-author:ColombeJames... | lld:pubmed |
| pubmed-article:20666410 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:20666410 | pubmed:day | 18 | lld:pubmed |
| pubmed-article:20666410 | pubmed:volume | 132 | lld:pubmed |
| pubmed-article:20666410 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:20666410 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:20666410 | pubmed:pagination | 11165-70 | lld:pubmed |
| pubmed-article:20666410 | pubmed:dateRevised | 2011-9-26 | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
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| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
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| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:meshHeading | pubmed-meshheading:20666410... | lld:pubmed |
| pubmed-article:20666410 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:20666410 | pubmed:articleTitle | Mechanism of the enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes. | lld:pubmed |
| pubmed-article:20666410 | pubmed:affiliation | Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA. | lld:pubmed |
| pubmed-article:20666410 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:20666410 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
